The differentials of four state
functions are often used in thermodynamics. E (often using the
symbol U), H, A, and G. Consider E first:
where the shorthand notation and is
used. By comparing the above two expressions, we see that
The so-called "Maxwell's Relations" are derived from
the fact that second order derivatives do not depend on the order
of differentiation:
Similarly,
If we do the same thing with
H, A, and G, we obtain
Now let's try an example of
using the above equations to determine a thermodynamic relationship.
Notice our expression for H has S, p, and N as the natural variables.
Suppose we wish to determine . We cannot
obtain this by reading from any of the above equations. To get
rid of the S-dependence in our expression for dH, we simply write
dS in terms of dT, dp, and dN: