Barcelona
- 25 Albert Jorquera
- 2 Martín Cáceres
- 3 Gerard Piqué
- 11 Bojan Krkić
- 15 Seydou Keita
- 16 Sylvinho
- 21 Aleksandr Hleb
- 27 Pedro Rodríguez
- 28 Sergio Busquets
- 29 Víctor Sánchez
- 30 Víctor Vázquez
Substitutes
- 13 José Pinto
- 7 Eidur Gudjohnsen
- 14 Thierry Henry
- 22 Eric Abidal
- 34 Xavi Torres
- 35 Abraham González
- 36 Alberto Botia
Coach
Josep Guardiola
Shakhtar
- 30 Andriy Pyatov
- 3 Tomáš Hübschman
- 5 Olexandr Kucher
- 7 Fernandinho
- 8 Jadson
- 19 Olexiy Gai
- 21 Olexandr Gladkiy
- 22 Willian
- 26 Răzvan Raţ
- 27 Dmytro Chygrynskiy
- 33 Darijo Srna
Substitutes
- 1 Bohdan Shust
- 10 Yevgen Seleznov
- 13 Vyacheslav Shevchuk
- 17 Luiz Adriano
- 18 Mariusz Lewandowski
- 25 Brandão
- 55 Volodymyr Yezerskiy
Coach
Mircea Lucescu
- Referee
- Michael Riley (ENG)
- Assistant referee
- Darren Cann (ENG)
- Fourth official
- Martin Atkinson (ENG)
- UEFA Delegate
- Metin Kazancıoğlu (TUR)
- UEFA Referee observer
- Dani Koren (ISR)
