Hafnium: the essentialsBrief description: most zirconium minerals contain 1 to 3% hafnium. Hafnium is a ductile metal with a brilliant silver lustre. Its properties are influenced considerably by the impurities of zirconium present. Of all the elements, zirconium and hafnium are two of the most difficult to separate. Hafnium is a Group 4 transition element. Because hafnium has a good absorption cross section for thermal neutrons (almost 600 times that of zirconium), has excellent mechanical properties, and is extremely corrosion resistant, it is used for nuclear reactor control rods. Hafnium carbide is the most refractory binary composition known, and the nitride is the most refractory metal nitride (m.p. 3310°C).
IsolationIsolation: hafnium extraction is always associated with its removal from zirconium as it is a contaminant of all zirconium minerals. Solvent extraction methods are used ot spearate the two metals but the process is not easy. These make use of the differential solubilities of the metal thiocyantes (thiocyanate is SCN-) in methyl isobutyl ketone. WebElements ShopWebElements now has an online shop at which you can buy periodic table posters, mugs, T-shirts, games, molecular models, and more. |
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